Hydrogen Evolution Electrocatalysis: Interface Modulation of MoS 2 /Metal Oxide Heterostructures for Efficient Hydrogen Evolution Electrocatalysis (Small 28/2020)

Layer-dependent electrocatalysis of MoS2 for hydrogen evolution.

The quantitative correlation of the catalytic activity with the microscopic structure of heterogeneous catalysts is a major challenge for the field of catalysis science. It requests synergistic capabilities to tailor the structure with atomic scale precision and to control the catalytic reaction to proceed through well-defined pathways. Here we leverage on the controlled growth of MoS2 atomical...

Highly branched cobalt phosphide nanostructures for hydrogen-evolution electrocatalysis

CoP nanostructures that exposed predominantly (111) crystal facets were synthesized and evaluated for performance as electrocatalysts for the hydrogen-evolution reaction (HER). The branched CoP nanostructures were synthesized by reacting cobalt(II) acetylacetonate with trioctylphosphine in the presence of trioctylphosphine oxide. Electrodes comprised of the branched CoP nanostructures deposited...

Electrocatalysis for the Hydrogen Economy

This chapter deals with the concept of “hydrogen economy”, which was introduced by John O.M’ Bockris in 1972. We summarize the fundamental principles and the progress for the reactions relevant to the hydrogen economy, namely the hydrogen and oxygen evolution for water electrolyzers, and the hydrogen oxidation and oxygen reduction for fuel cells. The activity of each reaction can be correlated ...

Atomically isolated nickel species anchored on graphitized carbon for efficient hydrogen evolution electrocatalysis

Hydrogen production through electrochemical process is at the heart of key renewable energy technologies including water splitting and hydrogen fuel cells. Despite tremendous efforts, exploring cheap, efficient and durable electrocatalysts for hydrogen evolution still remains as a great challenge. Here we synthesize a nickel-carbon-based catalyst, from carbonization of metal-organic frameworks,...

Hydrogen electrocatalysis: a basic solution.